Workbook for Organic Synthesis Strategy and Control
by Wyatt, Paul; Warren, StuartEdition: 1st
Format: Hardcover
Pub. Date: 2008-07-08
Publisher(s): Wiley
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Summary
This workbook accompanies Organic Synthesis: Strategy and Control, the bestselling advanced organic textbook Provides a complete course for advanced organic students and includes a graded set of problems, solutions and discussions to illustrate and develop the themes of each of the chapters in the textbook
Author Biography
Dr Paul Wyatt, School of Chemistry, University of Bristol, Bristol
Dr Wyatt is Director of Undergraduate Studies for the School of Chemistry at Bristol University and also Director of BRISTOL ChemLabS - a HEFCE Centre for Excellence in Teaching & Learning.
Dr Stuart Warren, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge
Dr Warren is the author of the bestselling textbooks Organic Synthesis: The Disconnection Approach (Wiley) and Organic Synthesis (OUP)
Table of Contents
| Preface | |
| Introduction: Selectivity. | |
| Planning Organic Syntheses: Tactics, Strategy and Control | |
| Chemoselectivity | |
| Regioselectivity: Controlled Aldol Reactions | |
| Stereoselectivity: Stereoselective Aldol Reactions | |
| Alternative Strategies for Enone Synthesis | |
| Choosing a Strategy: The Synthesis of Cyclopentenones | |
| Making Carbon-Carbon Bonds. | |
| The Ortho Strategy for Aromatic Compounds | |
| ?-Complexes of Metals | |
| Controlling the Michael Reaction | |
| Specific Enol Equivalents | |
| Extended Enolates | |
| Allyl Anions | |
| Homoenolates | |
| Acyl Anion Equivalents | |
| CarbonûCarbon Double Bonds. | |
| Synthesis of Double Bonds of Defined Stereochemistry | |
| Vinyl Anions | |
| Electrophilic Attack on Alkenes | |
| Vinyl Cations | |
| Allyl Alcohols: Allyl Cation Equivalents (and More) | |
| Stereochemistry. | |
| Control of Stereochemistry ù Introduction | |
| Diastereoselectivity | |
| Resolution | |
| The Chiral Pool: Asymmetric Synthesis with Natural Products as Starting Materials | |
| Asymmetric Induction I: Reagent-Based Strategy | |
| Asymmetric Induction II: Asymmetric Catalysis: Formation of CûO and CûN Bonds | |
| Asymmetric Induction III: Asymmetric Catalysis: Formation of CûH and CûC Bonds | |
| Asymmetric Induction IV: Substrate-Based Strategy | |
| Kinetic Resolution | |
| Enzymes: Biological Methods in Asymmetric Synthesis | |
| New Chiral Centres from Old: Enantiomerically Pure Compounds & Sophisticated Syntheses | |
| Strategy of Asymmetric Synthesis | |
| Functional Group Strategy. | |
| Functionalisation of Pyridine | |
| Oxidation of Aromatic Rings and of Enol(ate)s | |
| Functionality and Pericyclic Reactions: Nitrogen Heterocycles by Cycloadditions and Sigmatropic Rearrangements | |
| Synthesis and Chemistry of Azoles and other Heterocycles with Two or more Heteroatoms | |
| Tandem Organic Reactions | |
| Index | |
| Table of Contents provided by Publisher. All Rights Reserved. |
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